Methods and articles for image transfer

ABSTRACT

Image transfer articles, sheets and methods are disclosed. The image transfer articles and sheets can include or be configured to receive an image. The image can be capture on one or more ink or other marking receptive layers of the image transfer articles or sheets. In various examples, the image transfer articles provide decorative features in addition to the image. Such decorative features can include article portions bearing elements such as, but not limited to, metallic flakes, metallic-like flakes, glitter materials, sparkle materials, luminescent materials (e.g., having a glow-in-the-dark effect), pearlescent materials, reflective materials, or combinations thereof. In some examples, the image transfer articles include a vanishing layer configured to hold or sustain the image on a receptor element until the receptor element is washed a predetermined number of times.

CLAIM OF PRIORITY

This non-provisional patent application claims the benefit of priorityunder 35 U.S.C. §119(e) to U.S. Provisional Patent Application Ser. No.61/233,959, entitled “METHODS AND APPARATUS FOR IMAGE TRANSFER,” filedon Aug. 14, 2009, the specification of which is herein incorporated byreference in its entirety.

TECHNICAL FIELD

This patent document pertains generally to image transfer articles andmethods. More particularly, but not by way of limitation, this patentdocument pertains to image transfer articles providing variousdecorative effects and associated transfer methods.

BACKGROUND

Expressing creativity can bring about feelings of great satisfaction andself-worth. Finding a desired mode of self-expression can often be moredifficult than creating the expression itself. Image transfer technologyhas been, and continues to be, an ever-increasing mode of popularself-expression that allows one to find or create an image thatsatisfies a personal creative drive or at the least, to have apersonalized image that is unique to the individual end user. Thisimage, upon creation, can subsequently be transferred to a desiredreceptor element, which can be worn, carried, or displayed.

OVERVIEW

Although image transfer technologies have been in use for many years,these technologies remain difficult for the average end user to apply.Additionally, current image transfer technologies configured for at-homeuse do not provide images having internal decorative patterns. Furtheryet, these images can be limited to pre-created template options, whichlikely differ from a user-desired or user-created image. The inventorsof the present patent document have recognized the limitations of theart as it currently stands, and have addressed these needs.

Image transfer articles, sheets and methods are disclosed. The imagetransfer articles and sheets can include or be configured to receive animage comprising one or more markings. The image can be capture on oneor more ink or other marking receptive layers of the image transferarticles or sheets. By way of example, but not of limitation, the ink orother marking receptive layers can be configured to receive one or moremarkings from a printer, a copier, a marker, a pencil, a crayon, a dyesublimation process, a thermal pigment transfer process, or other toner,ink, or pigment-based imaging methods or apparatus. In various examples,the image transfer articles provide decorative features in addition tothe image. Such decorative features can include article portions bearingelements such as, but not limited to, metallic flakes, metallic-likeflakes, glitter materials, sparkle materials, luminescent materials(e.g., having a glow-in-the-dark effect), pearlescent materials,reflective materials, or combinations thereof, any of which can berevealed during the creation process by the end user.

To better illustrate the image transfer articles, sheets and methodsdisclosed in this patent document, a non-limiting list of examples isprovided here:

In Example 1, an image transfer article comprises a resin or adhesivelayer; a marking receptive layer; and a decorative layer, includingsurface-coated mica, positioned between the resin or adhesive layer andthe marking receptive layer.

In Example 2, the image transfer article of Example 1 is optionallyconfigured such that the decorative layer includes polyurethane.

In Example 3, the image transfer article of at least one of Examples 1or 2 optionally further comprises a silicone liner proximate the resinor adhesive layer, opposite the decorative layer.

In Example 4, the image transfer article of at least one of Examples 1-3is optionally configured such that the resin or adhesive layer includesan ethylene acrylic acid dispersion.

In Example 5, the image transfer article of at least one of Examples 1-4is optionally configured such that the decorative layer comprises ametallic layer including carbon black.

In Example 6, the image transfer article of at least one of Examples 1-5is optionally configured such that the decorative layer comprises ametallic layer including a plurality of metalized polyester particles.

In Example 7, the image transfer article of at least one of Examples 1-6is optionally configured such that the marking receptive layer comprisesa plurality of metalized polyester particles.

In Example 8, the image transfer article of at least one of Examples 1-7is optionally configured such that the decorative layer comprises ametallic layer including a luminescent pigment.

In Example 9, the image transfer article of at least one of Examples 1-8is optionally configured such that the marking receptive layer comprisesa luminescent pigment.

In Example 10, an image transfer sheet includes a plurality of imagetransfer articles as recited in at least one of Examples 1-9, and isoptionally configured such that

each image transfer article is at least partially defined by a die cutextending around a perimeter thereof, with each die cut extending atleast through the marking receptive layer and the decorative layer.

In Example 11, an image transfer sheet comprises a releasable liner orsubstrate; and one or more image transfer articles disposed on thereleasable liner or substrate, each image transfer article including, apre-formed image, and a resin or adhesive layer disposed between thereleasable liner or substrate and the pre-formed image, wherein eachimage transfer article has a perimeter defined by at least one die cutextending through the resin or adhesive layer to the releasable liner orsubstrate, the at least one die cut allowing each image transfer articleto separate individually from the releasable liner or substrate.

In Example 12, the image transfer sheet of Example 11 is optionallyconfigured such that the resin or adhesive layer comprises a luminescentpigment.

In Example 13, the image transfer sheet of at least one of Examples 11or 12 is optionally configured such that the resin or adhesive layercomprises a plurality of metalized polyester particles.

In Example 14, the image transfer sheet of at least one of Examples11-13 is optionally configured such that the resin or adhesive layerseparates from the releasable liner or substrate and attaches directlyto a receptor element to transfer the pre-formed image.

In Example 15, the image transfer sheet of at least one of Examples11-14 optionally further comprises a decorative layer disposed betweenthe pre-formed image and the resin or adhesive layer, and wherein thedie cut penetrates the decorative layer.

In Example 16, the image transfer sheet of Example 15 is optionallyconfigured such that the decorative layer comprises mica.

In Example 17, the image transfer sheet of Example 16 is optionallyconfigured such that the mica is coated with titanium oxide.

In Example 18, the image transfer sheet of Example 16 is optionallyconfigured such that the decorative layer includes carbon black.

In Example 19, the image transfer sheet of at least one of Examples15-18 is optionally configured such that the decorative layer comprisesa plurality of metalized polyester particles.

In Example 20, the image transfer sheet of at least one of Examples11-19 optionally comprises a marking receptive layer configured toreceive the pre-formed image and disposed on above the resin or adhesivelayer, and wherein the die cut penetrates the marking receptive layer.

In Example 21, the image transfer sheet of Example 20 is optionallyconfigured such that the marking receptive layer comprises a pluralityof metalized polyester particles.

In Example 22, the image transfer sheet of at least one of Example 20 or21 is optionally configured such that the marking receptive layercomprises a luminescent pigment.

In Example 23, a method comprises coating a base layer with a resin oradhesive layer; coating a marking receptive layer above the resin oradhesive layer, such that the resin or adhesive layer is disposedbetween the base layer and the marking receptive layer; and die cuttingthrough the marking receptive layer and the resin or adhesive layer.

In Example 24, the method of Example 23 is optionally configured suchthat coating the base layer with a resin or adhesive layer includescoating the base layer with a resin or adhesive layer comprising aplurality of coated aluminum metalized polyethylene terephthalateparticles.

In Example 25, the method of at least one of Examples 23 or 24optionally further comprises coating a decorative layer on the resin oradhesive layer, the decorative layer disposed between the resin oradhesive layer and the marking receptive layer.

In Example 26, the method of Example 25 is optionally configured suchthat coating a decorative layer includes coating a decorative layercomprising mica.

In Example 27, the method of at least one of Examples 25 or 26 isoptionally configured such that coating a decorative layer includescoating a decorative layer comprising titanium oxide coated mica.

In Example 28, the method of at least one of Examples 25-27 isoptionally configured such that coating a decorative layer includescoating a decorative layer comprising a plurality of coated aluminummetalized polyethylene terephthalate particles.

In Example 29, the method of at least one of Examples 25-28 isoptionally configured such that coating a decorative layer includescoating a decorative layer comprising a luminescent pigment.

In Example 30, the method of at least one of Examples 25-29 isoptionally configured such that coating a decorative layer includescoating a decorative layer comprising carbon black.

In Example 31, an image transfer sheet comprises a base layer; a resinor adhesive layer disposed on the base layer; a marking receptive layerdisposed above the resin or adhesive layer; and one or more imagetransfer articles, each article having a perimeter and including aportion of the image transfer sheet, the perimeter of each imagetransfer article defined by a set of perforations extending through thebase layer, the resin or adhesive layer and the printable markingreceptive layer, wherein each image transfer article is configured to beseparable from the remaining portions of the image transfer sheet at theset of perforations.

In Example 32, the image transfer sheet of Example 31 optionallycomprises a release layer disposed between the resin or adhesive layerand the base layer.

In Example 33, the image transfer sheet of at least one of Examples 31or 32 is optionally configured such that the set of perforations definea rectangular shape.

In Example 34, the image transfer sheet of at least one of Examples31-33 is optionally configured such that the set of perforations definea circular shape.

In Example 35, the image transfer sheet of at least one of Examples31-34 is optionally configured such that the one or more image transferarticles include at least a first image transfer article defined by afirst set of perforations and a second image transfer article defined bya second set of perforations.

In Example 36, the image transfer sheet of Example 35 is optionallyconfigured such that the first image transfer article has a first shapedefined by the first set of perforations and the second image transferarticle has a second shape defined by the second set of perforations.

In Example 37, the image transfer sheet of Example 36 is optionallyconfigured such that the first shape and the second shape aresubstantially similar.

In Example 38, the image transfer sheet of at least one of Examples31-37 is optionally configured such that the resin or adhesive layerincludes a copolymer dispersion.

In Example 39, the image transfer sheet of at least one of Examples31-38 is optionally configured such that the resin or adhesive layerincludes an ethylene acrylic acid copolymer.

In Example 40, the image transfer sheet of at least one of Examples31-39 is optionally configured such that the marking receptive layerincludes a polyamide material.

In Example 41, the image transfer sheet of at least one of Examples31-40 is optionally configured such that the resin or adhesive layerincludes a plurality of coated aluminum metalized polyethyleneterephthalate particles.

In Example 42, the image transfer sheet of Example 41 is optionallyconfigured such that the resin or adhesive layer includes carbon black.

In Example 43, the image transfer sheet of at least one of Examples 41or 42 is optionally configured such that the resin or adhesive layerincludes a luminescent material.

In Example 44, the image transfer sheet of at least one of Examples31-43 is optionally configured such that the resin or adhesive layercomprises a polyamide copolymer; ethylene acrylic acid; and a waxemulsion.

In Example 45, an image transfer sheet comprises one or more perforated,separable image transfer articles, wherein each image transfer articleincludes, a silicone liner; a resin or adhesive layer disposed on thesilicone; and a marking receptive layer disposed above the resin oradhesive layer.

In Example 46, the image transfer sheet of Example 45 optionallycomprises a plurality of coated aluminum metalized polyethyleneterephthalate particles disposed in the marking receptive layer.

In Example 47, a method comprises coating a base layer with a resin oradhesive layer; coating a marking receptive layer above the resin oradhesive layer, wherein the marking receptive layer is disposed on theresin or adhesive layer; and perforating the base layer, the resin oradhesive layer, and the marking receptive layer.

In Example 48, the method of Example 47 optionally comprises coating thebase layer with a release agent disposed between the base layer and theresin or adhesive layer.

In Example 49, the method of at least one of Example 47 or 48 isoptionally configured such that the base layer with a resin or adhesivelayer includes coating the base layer with a resin or adhesive layercomprising a plurality of coated aluminum metalized polyethyleneterephthalate particles.

In Example 50, the method of at least one of Examples 47-49 isoptionally configured such that coating the base layer with a markingreceptive layer includes coating the base layer with a marking receptivelayer including, a polyamide copolymer; ethylene acrylic acid; a waxemulsion; silica; and a polymethyl siloxane modified wax emulsion.

In Example 51, an image transfer sheet comprises a base layer; and amarking receptive layer including, marble; poly(ethylene oxide);polyethylene wax; and a hot melt, wherein the marking receptive layer isconfigured to transfer an image to a receptor element and furtherconfigured to dissipate the image upon washing the receptor element apredetermined number of times.

In Example 52, the image transfer sheet is optionally configured suchthat the marking receptive layer is configured to dissipate the imageupon a single washing.

In Example 53, the image transfer article, sheet, method or kit of anyone or any combination of Examples 1-52 is optionally configured suchthat all elements or options recited are available to use or selectfrom.

These and other examples, advantages, and features of the present imagetransfer articles, sheets and methods will be set forth in part infollowing Detailed Description. This Overview is intended to providenon-limiting examples of the present subject matter—it is not intendedto provide an exclusive or exhaustive explanation. The DetailedDescription is included to provide further information about the imagetransfer articles, sheets and methods disclosed in the present patentdocument.

BRIEF DESCRIPTION OF THE DRAWINGS

In the drawings, like numerals have been used to describe similarcomponents throughout the several views. Like numerals having differentletter suffixes have been used to represent different instances ofsimilar components. The drawings illustrate generally, by way ofexample, but not by way of limitation, various embodiments discussed inthe present patent document.

FIG. 1 pictorially illustrates a method of transferring an imagetransfer article, including an image, to a receptor element, accordingto at least one embodiment.

FIG. 2 illustrates an image transfer article, including an image,according to at least one embodiment.

FIG. 3 illustrates a cross-sectional view of an image transfer articletaken along a line similar to line A-A of FIG. 2, according to at leastone embodiment.

FIG. 4 illustrates a cross-sectional view of another image transferarticle taken along a line similar to line A-A of FIG. 2, according toat least one embodiment.

FIG. 5 illustrates a cross-sectional view of another image transferarticle taken along a line similar to line A-A of FIG. 2, according toat least one embodiment.

FIG. 6 illustrates a cross-sectional view of another image transferarticle taken along a line similar to line A-A of FIG. 2, according toat least one embodiment.

FIG. 7 illustrates a cross-sectional view of another image transferarticle taken along a line similar to line A-A of FIG. 2, according toat least one embodiment.

FIG. 8A illustrates an image transfer sheet, including a plurality ofdistinct image transfer articles separated by one or more die cuts,according to at least one embodiment.

FIG. 8B illustrates a cross-sectional view of an image transfer sheettaken along a line similar to line B-B of FIG. 8A, according to at leastone embodiment.

FIG. 9 illustrates an image transfer sheet, including a plurality ofdistinct images separated by perforations, according to at least oneembodiment.

FIG. 10 illustrates a cross-sectional view of an image transfer articletaken along a line similar to line A-A of FIG. 2, according to at leastone embodiment.

DETAILED DESCRIPTION

FIG. 1 illustrates an example image transfer article 100 including areceived image 102. The image 102 can be captured on one or more ink orother marking receptive layers 101 of the image transfer article 100,either before or after purchase of the article from a retailer.Subsequently, the image transfer article 100 can be applied to areceptor element 103, such as a t-shirt, gym bag, apron, pillowcase,jersey or other display means, and the image 102 can be attached andadhered thereto. Other options for the receptor element include, forexample, any textile, leather, ceramic, wool, glass, plastic, metal orcanvas material.

The present image transfer article 100 provides outwardly-viewabledecorative features 190 in addition to the image 102. Such decorativefeatures 190 can include article portions bearing elements such as, butnot limited to, metallic flakes, metallic-like flakes, glittermaterials, sparkle materials, luminescent materials (e.g., having aglow-in-the-dark effect), pearlescent materials, reflective materials,or combinations thereof.

FIG. 2 illustrates an isometric view of an example image transferarticle 200, including a received image 202. The image transfer article200 further includes one or more layers 204 possessing functionalproperties, decorative properties, or both functional and decorativeproperties. In the example shown, the image transfer article 200includes a releasable liner or substrate 205 as one of the layers 204.In various examples, the releasable liner or substrate 205 supportsother image transfer article layers during fabrication, imaging (i.e., amarking process), or image transfer. For instance, during imagetransfer, the releasable liner or substrate 205 can provide a heatbarrier when the image 202 is being adhered to a receptor element. Asanother example, during fabrication, coating techniques such as dipping,painting, spraying, gravure, off-set, reverse roll, extrusion or meltextrusion, or coating apparatus such as Meyer rods, slot dies, rollers,knifes or other blades, curtains or slides, can be used to apply imagetransfer article layers 204 to the releasable liner or substrate 205.

Due to the structural configurations of the present image transferarticles 200, a hand iron may be used to apply the image 202 to areceptor element within the confines of one's own home. As a result, aconsumer is not locked into the narrow choice of apparel at commercialcopy service locations. Instead, the consumer can simply copy, print orotherwise reproduce a desired image onto a present transfer article 200,select from a wide variety of fabric garments readily available inretail stores or within the home, and effectuate an image transfer.

FIG. 3 illustrates a cross-sectional view of an image transfer article300 taken along a line similar to line A-A of FIG. 2, according to atleast one example of the present subject matter. The image transferarticle 300 can include one or more of an ink or other marking receptivelayer 310, a decorative layer 311, and a resin or adhesive layer 312. Insome examples, the ink or other marking receptive layer 310 isconfigured to receive ink or toner from a printer or copier source. Inother examples, the marking receptive layer 310 is configured to receiveone or more markings generated by a marker, a pencil, a crayon, a dyesublimation process, a thermal pigment transfer process, or other toner,ink, or pigment-based imaging methods or apparatus. In various examples,the image transfer article 300 can include a releasable liner orsubstrate 305. The releasable liner or substrate 305, if present, canprovide a base layer. Coatings applied to the base layer can form thedecorative 311 and functional layers (e.g., the resin or adhesive layer312 and/or the marking receptive layer 310) of the image transferarticle 300.

The process of applying an image to a receptor element depends, at leastin part, on the structure of the image transfer article 300 bearing theimage. In various examples, as noted above, the image transfer article300 can include decorative features 390, which, depending on theirconcentration, may form an opaque, semi-opaque, or other non-transparentlayer. Using the chemical formulations disclosed herein, decorativeimage transfer articles having good clarity, sharpness and color arepossible. In such examples, the image can be located above thenon-transparent layer including the decorative features 390 and removalof the releasable liner or substrate 305 can expose a layer 312including a resin or adhesive. The resin or adhesive layer 312 can beapplied directly to a receptor element, such as a t-shirt, gym bag,apron, pillowcase, jersey, or other textile, leather ceramic, wool,glass, plastic, metal or canvas display means, when being transferredthereto and before the heating and/or pressure portion of the imagetransferring process. After applying the adhesive layer to the receptorelement, the previously-removed releasable liner or substrate 305 oranother releasable overlay article can be used to cover a top exposedsurface of the image transfer article 300 and provide a heat barrierduring the transfer process. After the heat and/or pressure are applied,the liner or substrate 305 or other removable overlay article can bepeeled away from the image at various hot or cold temperatures anddiscarded. In some examples, the exposed surface of the image transferarticle 300 is an ink or other marking receptive layer 310 bearing areceived image. This configuration is sometimes referred to as a “peelfirst” image transfer article or structure.

In some examples, the releasable liner or substrate 305 is configured toremain as part of the image transfer article until post-transfer (to areceptor element), and provides a heat barrier during the heating and/orpressure application portions of the image transferring process. In onesuch example, the ink or other marking layer 310 bears a mirrored image,which can be applied directly to the receptor element, such as a t-shirtor other textile article, when being transferred thereto and before theheating and/or pressure portions of the image transferring process.After applying the ink or other marking layer 310 against the receptorelement, heat and/or pressure are applied, and subsequently thereleasable liner or substrate 305 can be removed (e.g., peeled) from theother layers of the image transfer article 300. This configuration issometimes referred to as a “peel after” image transfer article orstructure, a “regular” image transfer article or structure, or a“reverse image” or “mirror” transfer article or structure.

In various examples, the resin or adhesive layer 312 can include anadhesive compound to attach the image to the receptor element. Compoundsused for the resin or adhesive layer 312 can include, but are notlimited to, an ethylene copolymer such as ethylene acrylic acid (EAA),ethylene methacrylic acid (EMAA), or ethylene-vinyl acetate (EVA). Insome examples, the EAA or EMAA includes a melt index from about 5 toabout 2500, such as from about 10 to about 1300. In some examples, theEAA or EMAA includes an acrylic acid concentration from about 0% toabout 30%, such as from about 1% to about 20% for emulsion purposes. Insome examples, the EAA, EMAA or EVA includes a melt point temperaturebetween about 43° C. to about 160° C. In some examples, the resin oradhesive layer 312 comprises EVA with a vinyl acetate content of about3% to about 45%. In some examples, an EVA resin or adhesive layer alsoincludes a wax emulsion to provide better adhesion and flexibility tothe image transfer article 300. In some examples, an EVA resin oradhesive layer 312 includes a carboxylic element to provide increasedadhesion and toughness to the image transfer article 300.

FIG. 4 is a cross-sectional view of an image transfer article 420 takenalong a line similar to line A-A of FIG. 2 and including a portionexhibiting pearlescent effects 490, according to at least one example ofthe present subject matter. The cross-section shows that the imagetransfer article 420 can include one or more of a releasable liner orsubstrate 405, a resin or adhesive layer 421, a decorative layer 422,and optionally an ink or other marking receptive layer 423. If nodistinct ink or other marking receptive layer 423 is present, a resin oradhesive layer 421 including EAA with or without a cross-linker (e.g.,XAMA®7 (polyfunctional aziridine)) can receive markings, such as laserjet markings, for example.

The resin or adhesive layer 421 can operate to attach an image receivedby the image transfer article to a receptor element. As discussed above,the resin or adhesive layer 421 can be coated onto a top surface of thereleasable liner or substrate 405 and can include an ethylene copolymer,such as, but not limited to, ethylene acrylic acid (EAA), ethylenemethacrylic acid (EMAA), or ethylene-vinyl acetate (EVA).

The decorative layer 422 can include pearlescent materials 490, suchthat when the image transfer article 420 is applied to a receptorelement, the transferred image includes a pearlescent background. Insome examples, the pearlescent decorative layer 422 can be coated ontothe resin or adhesive layer 421. In some examples, the pearlescentdecorative layer 422 includes a urethane polymer and a pearlescentpigment, such as coated mica particles. In some examples, thepearlescent decorative layer 422 includes an ethoxylated non-ionicfluorosufactant in addition to the urethane polymer and pearlescentpigment. Optionally, the pearlescent decorative layer 422 can includeiridescent-effect inorganic particles detectable via light ortemperature. In some examples, the pearlescent pigment can be coatedwith the resin or adhesive layer 421 or the ink or other markingreceptive layer 423, such that one or more defined layers are formedsimultaneously or substantially simultaneously.

In some examples, the ink or other marking receptive layer 423 can becoated onto the decorative layer 422. The ink or other marking receptivelayer 423 can comprise pores for receiving ink jet or laser jet ink, forexample. One or both of the ink or other marking receptive layer 423 orthe decorative layer 422 can also include at least one bindingcomposition in an amount sufficient to chemically bind the ink withinthe layer. In various examples, the at least one binding compositionincludes a glass transition temperature (T_(g)) between about −40° C. upto about 30° C., which the present inventors have found can reduce orinhibit flaking and cracking of a transferred image. The ink or othermarking receptive layer 423 can optionally further include one or moreof isopropyl alcohol, an ultrafine copolyamide, SMA (Styrene MaleicAnhydride resin), colloidal alumina, colloidal silica, polyester, apolyamide copolymer, polyurethane (optionally including surfactants suchas Triton X-100, Triton 405, CT110, or Surfynol), acrylics with a glasstransition temperature (T_(g)) between about −40° C. up to about 70° C.,vinyl acetate, polyethylene oxide (with or without plasticizers, such asup to about 30% plasticizer), a cationic polymer, an ionic or non-ionicdie-fixing agent, a polymeric ammonium compound or surfactants includingan oxtylphenol ethoxylate non-ionic surfactant and an ethoxylatednon-ionic fluorosurfactant, silica particles, cationic silica, clay,cationic-modified silica (e.g., JETCOAT®30) or other cationic polymer.Additional components such as inorganic fillers, anti-curl agents,surfactants, plasticizers, humectants, UV absorbers, opticalbrighteners, light fastness enhancers, polymeric dispersants, dyemordents or leveling agents, may also be present in the ink or othermarking receptive layer 423.

FIG. 5 is a cross-sectional view of an image transfer article 530 takenalong a line similar to line A-A of FIG. 2 and including a metalliceffect 590, according to at least one example of the present subjectmatter. The cross-section shows that the image transfer article 530 caninclude one or more of a releasable liner or substrate 505, a resin oradhesive layer 531, a decorative layer 532, and optionally an ink orother marking receptive layer 533. If no distinct ink or other markingreceptive layer 533 is present, a resin or adhesive layer 531 includingEAA with or without a cross-linker (e.g., XAMA®7 (polyfunctionalaziridine)) can receive markings, such as laser jet markings, forexample.

The resin or adhesive layer 531, if present, can include materials toadhere a received image to a receptor element. In some examples, thereceptor element includes a building wall, such as when the imagetransfer article 530 is used as a wallpaper. As discussed above, theresin or adhesive layer 531 can be coated into a top surface of thereleasable liner or substrate 405 and can include an ethylene copolymer,such as, but not limited to, ethylene acrylic acid (EAA), ethylenemethacrylic acid (EMAA), or ethylene-vinyl acetate (EVA).

The decorative layer 532 can include metallic or metallic-type materials590 (e.g., titanium oxide and/or dioxide coated mica or tin oxide coatedmica) such that when the image transfer article 530 is applied to areceptor element, the transferred image includes a metallic effect,either in the background of the image or integrated with or about areceived image. In some examples, the metallic decorative layer 532 canbe coated onto the resin or adhesive layer 531. In some examples, themetallic decorative layer 532 can include a urethane polymer, apearlescent pigment or carbon black. In some examples, the metallicdecorative layer 532 can include an ethoxylated non-ionicfluorosufactant in addition to the urethane polymer, pearlescent pigmentor carbon black. Advantageously, the metallic decorative layer 532 canbe formed without requiring a chemical reaction to take place. As aresult, non-complex manufacturing and non-expensive manufacturingtechniques can be used to create the metallic decorative layer 532.

In some examples, the ink or other marking receptive layer 533 can becoated onto the decorative layer 532. The ink or other marking receptivelayer 533 can comprise pores for receiving ink jet or laser jet ink, forexample. One or both of the ink or other marking receptive layer 533 orthe decorative layer 532 can also include at least one bindingcomposition in an amount sufficient to chemically bind the ink withinthe layer. In various examples, the at least one binding compositionincludes a glass transition temperature (T_(g)) between about −40° C. upto about 30° C., which the present inventors have found can reduce orinhibit flaking and cracking of a transferred image. The ink or othermarking receptive layer 533 can optionally further include isopropylalcohol, an ultrafine copolyamide, SMA (Styrene Maleic Anhydride resin),colloidal alumina, colloidal silica, polyester, a polyamide copolymer,polyurethane (optionally including surfactants such as Triton X-100,Triton 405, CT110, or Surfynol), acrylics with a glass transitiontemperature (T_(g)) between about −40° C. up to about 70° C., vinylacetate, polyethylene oxide (with or without plasticizers, such as up toabout 30% plasticizer), a cationic polymer, an ionic or non-ionicdie-fixing agent, a polymeric ammonium compound or surfactants includingan oxtylphenol ethoxylate non-ionic surfactant and an ethoxylatednon-ionic fluorosurfactant, silica particles, cationic silica, clay,cationic-modified silica (e.g., JETCOAT®30) or other cationic polymer.

FIG. 6 is a cross-sectional view of an image transfer article 640 takenalong a line similar to line A-A of FIG. 2 and including a sparkleeffect 690, according to at least one example of the present subjectmatter. The cross-section shows that the image transfer article 640 caninclude one or more of a releasable liner or substrate 605, a resin oradhesive layer 641, a decorative layer 642, and optionally an ink orother marking receptive layer 643. If no distinct ink or other markingreceptive layer 643 is present, a resin or adhesive layer 641 includingEAA with or without a cross-linker (e.g., XAMA®7 (polyfunctionalaziridine)) can receive markings, such as laser jet markings, forexample.

The resin or adhesive layer 641, if present, can operate to attach animage received by the image transfer article to a receptor element. Asdiscussed above, the resin or adhesive layer 641 can be coated onto atop surface of the releasable liner or substrate 605 and can include anethylene copolymer, such as, but not limited to, ethylene acrylic acid(EAA), ethylene methacrylic acid (EMAA), or ethylene-vinyl acetate(EVA).

The decorative layer 642 can include metallic particles or metallic-likeparticles 690 such that when the image transfer article 640 is appliedto a receptor element, the transferred image includes sparklesintegrated with or about a received image. In some examples, thedecorative layer 642 can be coated onto a top surface of the resin oradhesive layer 641. In some examples, the decorative layer 642 caninclude a urethane polymer and the sparkle material. In some examples,the sparkle material includes metallic or metallic-like particles withparticle sizes of about 0.004 inches or less. In some examples, thesparkle material includes coated aluminum metalized polyethyleneterephthalate particles. In some examples, the decorative sparkle layer642 includes an ethoxylated non-ionic fluorosufactant in addition to theurethane polymer and sparkle material.

The ink or other marking receptive layer 643 can be coated onto thedecorative layer 642. The ink or other marking receptive layer 643 cancomprise pores for receiving ink jet or laser jet ink, for example. Oneor both of the ink or other marking receptive layer 643 or thedecorative layer 642 can also include at least one binding compositionin an amount sufficient to chemically bind the ink within the layer. Invarious examples, the at least one binding composition includes a glasstransition temperature (T_(g)) between about −40° C. up to about 30° C.,which the present inventors have found can reduce or inhibit flaking andcracking of a transferred image. In some examples, the ink or othermarking receptive layer 643 can optionally further include isopropylalcohol, an ultrafine copolyamide, SMA (Styrene Maleic Anhydride resin),colloidal alumina, colloidal silica, polyester, a polyamide copolymer,polyurethane (optionally including surfactants such as Triton X-100,Triton 405, CT110, or Surfynol), acrylics with a glass transitiontemperature (T_(g)) between about −40° C. up to about 70° C., vinylacetate, polyethylene oxide (with or without plasticizers, such as up toabout 30% plasticizer), a cationic polymer, an ionic or non-ionicdie-fixing agent, a polymeric ammonium compound or surfactants includingan oxtylphenol ethoxylate non-ionic surfactant and an ethoxylatednon-ionic fluorosurfactant, silica particles, cationic silica, clay,cationic-modified silica (e.g., JETCOAT®30) or other cationic polymer.

FIG. 7 is a cross-sectional view of an image transfer article 750 takenalong a line similar to line A-A of FIG. 2, according to at least oneexample of the present subject matter. The cross-section shows the imagetransfer article 750 can include one or more of a releasable liner orsubstrate 705, a decorative resin or adhesive layer 751, and optionallyan ink or other marking receptive layer 752. If no distinct ink or othermarking receptive layer 752 is present, a decorative resin or adhesivelayer 751 including EAA with or without a cross-linker (e.g., XAMA®7(polyfunctional aziridine)) can receive markings, such as laser jetmarkings, for example. In various examples, the base releasable liner orsubstrate 705 can include a release agent, such as silicone. In someexamples, the releasable liner or substrate 705 does not includesilicone.

The decorative resin or adhesive layer 751 can operate to adhere animage received by the image transfer article 750 to a receptor element.In some examples, the decorative resin or adhesive layer 751 is coatedonto the releasable liner or substrate 705. In some examples, asdiscussed above, the decorative resin or adhesive layer 751 includes anethylene copolymer, such as, but not limited to, ethylene acrylic acid(EAA), ethylene methacrylic acid (EMAA), or ethylene-vinyl acetate(EVA).

In addition to resin and the associated adhering function, thedecorative resin or adhesive layer 751 can also include one or moredecorative materials. In some examples, the decorative resin or adhesivelayer 751 includes a glitter material 790. The glitter material caninclude metallic or metallic-like particles with particle sizes of about0.002 inches, for example. In some examples, the glitter material caninclude coated aluminum metalized polyethylene terephthalate particles.In some examples, the decorative resin or adhesive layer 751 can includeluminescent materials 790 such that upon transfer of an image to areceptor element, the image, or portions thereof, glow in the darkincluding fluorescent and/or phosphorescent material such as, forexample, alkaline earth aluminates. In some examples, the decorativeresin or adhesive layer 751 can include both glitter particles and glowpigment.

The ink or other marking receptive layer 752 can be located proximatethe decorative resin or adhesive layer 751, opposite the releasableliner or substrate 705. In various examples, the ink or other markingreceptive layer 752 is coated onto the decorative resin or adhesivelayer 751. The ink or other marking receptive layer 752 can include oneor more of a polyamide copolymer, polyurethane, amide solids, ethyleneacrylic acid, micronized polyethylene wax, a poly-dimethyl siloxanemodified wax emulsion, or polyvinylpyrrolidone. The ink or other markingreceptive layer 752 can optionally further include one or more ofisopropyl alcohol, an ultrafine copolyamide, SMA (Styrene MaleicAnhydride resin), colloidal alumina, colloidal silica, polyester, apolyamide copolymer, polyurethane (optionally including surfactants suchas Triton X-100, Triton 405, CT110, or Surfynol), acrylics with a glasstransition temperature (T_(g)) between about −40° C. up to about 70° C.,vinyl acetate, polyethylene oxide (with or without plasticizers, such asup to about 30% plasticizer), a cationic polymer, an ionic or non-ionicdie-fixing agent, a polymeric ammonium compound or surfactants includingan oxtylphenol ethoxylate non-ionic surfactant and an ethoxylatednon-ionic fluorosurfactant, silica particles, cationic silica, clay,cationic-modified silica (e.g., JETCOAT®30) or other cationic polymer.

Upon transfer and application of a received image to a receptor element,the ink or other marking receptive layer 752 can provide a “soft touch”to the transferred image, such that it is difficult to discern by touchwhere the perimeter of an image transfer article begins and ends on areceptor element, such as a fabric or other textile material. The “softtouch” nature of the transferred image can provide more comfort wherethe receptor element is worn by a user, such as a t-shirt or infantclothing for example, and can be made possible through the use of a waxemulsion. The present inventors have found that the incorporation of awax emulsion into one or both of the ink or other marking receptivelayer 752 or the resin or adhesive layer 751 can provide betterflexibility and feel to the image transfer article 750.

In some examples, the ink or other marking receptive layer 752 caninclude decorative materials such as glitter particles, glow pigment, orboth glitter particles and glow pigment. In the illustrated imagetransfer article 750, an image can be applied to the ink or othermarking receptive layer 752 as a mirror or reverse image of the imagethat is expressed after the image is transferred to a receptor element.Optionally, the glitter particles, glow pigment, or both the glitterparticles and glow pigment are located in a layer distinct from theresin or adhesive layer 751 and the ink or other marking receptive layer752.

FIG. 8A illustrates an image transfer sheet 860, according to at leastone example of the present subject matter. The image transfer sheet 860can include a releasable liner or substrate 805, one or more layers 864on the liner or substrate 805, and one or more depth-controlled die cuts865 at least partially defining one or more individual image transferarticles 866. The image transfer sheet 860 can include an ink or othermarking receptive layer 863 positioned above the releasable liner orsubstrate 805. In some examples, the ink or other marking receptivelayer 863 includes ink indicia forming an image 867 thereon. In someexamples, one or more of the images 867 are added by a user of the imagetransfer sheet 860. Such images may be applied using an ink jet printerfor example, but the addition of an image 867 is not so limited. Manualdrawing with a pen, spray paint, brushing, stenciling or other markinginstrument include other non-limiting examples of how a user may add animage to the ink or other marking receptive layer 863 of the imagetransfer sheet 860.

FIG. 8B illustrates a cross-sectional view of an image transfer sheet860 taken along a line similar to line B-B of FIG. 8A, according to atleast one example of the present subject matter. The image transfersheet 860 can include a releasable liner or substrate 805 and one ormore layers 864 making up one or more image transfer articles 866, eachincluding one or more of a resin or adhesive layer 861, a decorativelayer 862, and optionally an ink or other marking receptive layer 863.The cross-sectional view of the image transfer sheet 860 furtherillustrates a controlled-depth of one or more die cuts 865. Thedepth-controlled die cuts 865 can penetrate the ink or other markingreceptive layer 863, the decorative layer 862, and the resin or adhesivelayer 861.

Upon applying an image to the ink or other marking receptive layer 863,whether pre-printed prior to purchase or printed by a user, the die cuts865 can allow each image transfer article 866 to be individuallyreleased from the liner or substrate 805. In various examples, anindividual image transfer article 866 can be removed from the sheet 860,thus separating it from the releasable liner 805. The image transferarticle 866 can then be applied to a receptor element such that theresin or adhesive layer 861 contacts a surface of the receptor element.A heat barrier, such as a tack resistant silicone overlay sheet, can beplaced over an exposed image 867 received by layer 863 of the individualimage transfer article 866, and heat and/or pressure can subsequently beapplied to attach the image 867 to the receptor element. The appliedheat and/or pressure can melt portions of the resin or adhesive layer861 to attach the image 867 to the receptor element, the heat can alsomelt resin at or near the ink or other means forming the image toencapsulate and embed the ink therein. The heat barrier can then beremoved, post application of heat and/or pressure, revealing thetransferred image on the receptor element.

In various examples, the image transfer sheet can include one or moredie cuts that defines one or more image transfer articles, eachincluding one or more of a releasable liner or substrate, a resin oradhesive layer, or and an ink or other marking receptive layer, such asis described in association with FIG. 7. The die cuts can penetrate theink or other marking receptive layer and the resin or adhesive layer.Application of an image to a receptor element can include applying theink or other marking receptive layer to the receptor element, applyingheat and/or pressure to the releasable liner or substrate and removingthe releasable liner or substrate to reveal the image on the receptorelement. In such examples, the image applied to the image transfersheet, or the individual image transfer articles, is a reverse image ofthat revealed once the image is transferred (post application of heatand/or pressure) to the receptor element.

In various examples, a die-cut image transfer sheet is included in a kitof pre-printed image transfer sheets (i.e., image transfer sheetsprinted prior to purchase at a retailer). Pre-printed die cut imagetransfer sheets may or may not include an ink receptive layer. In someexamples, images are applied to the image transfer sheets using ink jetprinters, offset printers, flexographic printers and the associated inks(e.g., non-plastisol inks), thermal wax ribbon printers and copies,laser toner copiers, etc. In various embodiments, pre-printed imagetransfer sheets include one or more of the following features orcomponents: luminescent pigments, titanium oxide and/or dioxide coatedmica, tin oxide coated mica, carbon black, metallic particles such asaluminum metalized polyethylene terephthalate particles, or a vanishingresin or adhesive layer as further described below.

In use, the pre-printed image transfer articles can simply be peeledfrom the die cut image transfer sheet, after purchase, positioned on thereceptor element, and then heated to transfer the pre-printed image viaeither a “regular” or “peel first” method, as discussed above. In someexamples, a disposable barrier (e.g., a tack resistant silicone overlaysheet) is used between the heat source and the image transfer articlewhen transferring the image.

In some examples, pre-printed image transfer sheets are included in akit. In some examples, a pre-printed image transfer sheet kit includesone or more image transfer sheets bearing images related to a particulartheme, such as a holiday, special occasion or a composite image whereeach image transfer article of an image transfer sheet is a portion ofthe composite image. The kit can further include instructions on a howto transfer the image to a receptor element, such as instructions andoptions on how to properly position image transfer articles on thereceptor element for a composite image. In some examples, the kit caninclude one or more disposable heat barrier sheets.

FIG. 9 illustrates an image transfer sheet 970, according to at leastone example of the present subject matter. The sheet 970 includes aplurality of image transfer articles 976 at least partially defined byone or more perforation cuts 975. One or more layers of the sheet 970are shown peeled back from a releasable liner or substrate 905 at acorner of the sheet to illustrate the perforation cuts 975, which extendthrough all the layers of the image transfer sheet, including thereleasable liner or substrate 905. The perforated cuts 975 can allowremoval of an individual image transfer article 976 from the sheet 970.As an example, the image transfer article 976 a is shown removed fromthe sheet 970.

Options for image transfer sheets 970 including one or more imagetransfer articles 976 at least partially defined by perforation cuts arenumerous. In some examples, removed image transfer articles 976 includethe releasable liner or substrate 905, as well as, other functional ordecorative layers of the image transfer sheet 970. In some examples,each image transfer article 976 includes one or more of an ink receptivelayer, a decorative layer, a resin or adhesive layer, a decorative resinor adhesive layer, or a releasable liner or substrate 905, such as thecombinations and options described throughout this patent document. Invarious some examples, the image transfer sheet 970 includes pre-printedimages, images printed by the user, or pre-printed images and areas oneach image transfer article allowing additional image application by theuser. It is to be understood that various sized and shaped imagetransfer articles can be created with the depth-controlled die cuts orperforation cuts without departing from the scope of the present subjectmatter including, but not limited to, shapes associated with birthdays,anniversaries, holidays or religious occasions, for example. Previously,end users have been limited to using a pre-set design or a single imagethat they have printed to the image transfer sheet. This invention opensup an entirely new method for end users to customize their end product.The end user can now configure a unique image regardless of whether theyare using a pre-printed set of images or printing their own.

FIG. 10 illustrates an image transfer article 1080 taken along a linesimilar to line A-A of FIG. 2, according to at least one example of thepresent subject matter. The article 1080 can include a base layer 1082(e.g., releasable liner or substrate) and an at least partiallyvanishing layer 1081. In some examples, the vanishing layer 1081includes one or more layers coated on the base layer 1082. In someexamples, the vanishing layer 1081 is back-treated, such as with acorona treatment or water. The image transfer article 1080 is configuredto receive an image, such as from an ink jet printer, and transfer theimage to a receptor element, for example a t-shirt. The transfer processtransfers the image and the vanishing layer 1081.

The vanishing layer 1081 is configured to hold or sustain the image onthe receptor element until the receptor element is washed apredetermined number of times (e.g., a single washing or multiplewashings). In some examples, the pores of, and binding compositionamounts within, the vanishing layer 1081 are adjusted to achieve thepredetermined washout number. In various examples, the vanishing layer1081 includes a thermoplastic, water-soluble resin which provides a lowbond to receptor elements, such as fabric, and is ink-jet printable. Thewater-soluble nature of the resin can allow received ink or other imagepigment to wash out after the predetermined number of times. Thethermoplastic nature of the resin allows for easy heat transfer with lowbond. In use, the received image pigment acts as a collating agent that,when washed out, takes at least a portion of bond with it. In variousexamples, at least one binding composition in a low concentrationrelative to the vanishing layer 1081 weight is used to chemically bindthe image pigment within the layer without precluding washability anddye drying.

Upon washing the predetermined number of times, the image disappears,thus allowing the t-shirt to be redecorated with another image, such asvia the image transfer articles and methods described throughout thispatent document. Such an image transfer article 1080 allows temporarydecoration of receptor elements such as, but not limited to, t-shirts,hats, socks, hand bags and backpacks. In one example, temporarydecoration of a receptor element may include decorating a receptorelement with a holiday theme, washing the receptor element to erase theholiday theme after the holiday and then repeating the temporarydecoration of the receptor element for subsequent holidays or events.

In various examples, a temporary image transfer kit can include one ormore pre-printed vanishing image transfer sheets (including one or morearticles at least partially defined by one or more die or perforationcuts) or articles that include a theme, such as, a Halloween theme or abirthday theme, for example. In some examples, the kit can include areceptor element upon which to transfer the pre-printed images of thevanishing image transfer articles or sheets. In some examples, eachvanishing image transfer article or sheet can include a base layercoated with a vanishing layer solution including water, isopropylalcohol, fine particle marble, poly(ethylene oxide) having a molecularweight between about 100,000 to about 8 million, a large particlepolyethylene wax and a hot melt. In some examples, the base layer iscoated twice to form the vanishing layer.

EXPERIMENTAL EXAMPLES

In order that the present image transfer articles, sheets and methodscan be more fully understood, the following examples are given by way ofillustration but not limitation.

Experimental Example 1 Articles or Sheets Including Pearlescent Effects

Coat Weight (grams per square Coating Approx. meter (gsm) dry) SolidsRod Size Resin or Formula In some examples, between 40.00% 26 Adhesive Aabout 2.5 to 75; in some Layer examples, between about 6 to 60; and insome examples, between about 12 to 35 Decorative Formula In someexamples, between 51.94% 32 Layer E about 19 to 82; in some examples,between about 24 to 59; and in some examples, between about 26 to 30 Inkor Formula In some examples, between 26.50% 30 Other C about 2 to 80; insome Marking examples, between about 4 Receptive to 45; and in someexamples, Layer between about 6 to 30 Coated on releasable liner orsubstrate

Experimental Example 2 Articles or Sheets Including Metallic Effects

Coat Weight (grams per square Coating Approx. meter (gsm) dry) SolidsRod Size Resin or Formula In some examples, between 40.00% 26 Adhesive Aabout 2.5 to 75; in some Layer examples, between about 6 to 60; and insome examples, between about 12 to 35 Decorative Formula In someexamples, between 51.85% 32 Layer D about 19 to 82; in some examples,between about 24 to 59; and in some examples, between about 26 to 30 Inkor Formula In some examples, between 26.50% 30 Other C about 2 to 80; insome Marking examples, between about 4 Receptive to 45; and in someexamples, Layer between about 6 to 30 Coated on releasable liner orsubstrate

Experimental Example 3 Articles or Sheets Including Sparkle Effects

Coat Weight (grams per square Coating Approx. meter (gsm) dry) SolidsRod Size Resin or Formula In some examples, between 40.00% 26 Adhesive Aabout 2.5 to 75; in some Layer examples, between about 6 to 60; and insome examples, between about 12 to 35 Decorative Formula In someexamples, between 51.97% 34 Layer B about 19 to 82; in some examples,between about 24 to 59; and in some examples, between about 40 to 46 Inkor Formula In some examples, between 26.50% 30 Other C about 2 to 80; insome Marking examples, between about 4 to Receptive 45; and in someexamples, Layer between about 6 to 30 Coated on releasable liner orsubstrate

Experimental Example 4 Articles or Sheets Including Glitter Effects

Coat Weight (grams per square Coating Approx. meter (gsm) dry) SolidsRod Size Decorative Formula In some examples, between 36.06% 55 Resin orF about 5 to 130; in some Adhesive examples, between about 10 Layer to90; and in some examples, between about 20 to 65 Ink or Formula In someexamples, between 33.00% 34 Other G about 4 to 100; in some Markingexamples, between about 8 Receptive to 75; and in some examples, Layerbetween about 15 to 45 Coated on releasable liner or substrate

Experimental Example 5 Articles or Sheets Including Glow Effects

Coat Weight (grams per square Coating Approx. meter (gsm) dry) SolidsRod Size Decorative Formula In some examples, between 39.54% 36 Resin orI about 3 to 108; in some Adhesive examples, between about 10 Layer to80; and in some examples, between about 15 to 45 Ink or Formula In someexamples, between 33.00% 34 Other G about 4 to 100; in some Markingexamples, between about 8 Receptive to 75; and in some examples, Layerbetween about 15 to 45 Coated on releasable liner or substrateOptionally, EAA/EVA/PE can be coated from about 6 gsm to about 70 gsm,plus 20% glow pigement.

Experimental Example 6 Articles or Sheets Including Vanish Effects

Coat Weight (grams per square Coating Approx. meter (gsm) dry Solids RodSize Vanishing Formula In some examples, between 22.90% 42 Layer H about3 to 110; in some examples, between about 5 to 85; and in some examples,between about 10 to 50 Optional Formula In some examples, between 22.90%26 Second H about 3 to 110; in some Vanishing examples, between about 5Layer to 85; and in some examples, between about 10 to 50 Coated onreleasable liner or substrate

Experimental Formulas

Raw Material Weight Percentage Formula A Ethylene Vinyl Acetate (EVA)100.00000% Dispersion or EVA Melt Extruded or Blend EVA/EAA orEVA/Surlin Solids: 38% to 42% Formula B Polyurethane Dispersion 50% to90% Glitter 10% to 35% Surfactant 0% to 2% Solids: 50% to 54% Formula CR.O. Water 48% to 52% Silica  2% to 22% Non-Ionic Surfactant 0% to 2%Polyamide Polymer  3% to 30% Polyurethane Dispersion  9% to 40% Dye Fix 0% to 15% Surfactant 0% to 2% Solids: 24.5% to 28.5% Formula DPolyurethane Dispersion 50% to 90% Metallic Effect Pigment 18% to 22%Carbon Black Dispersion 0% to 2% Surfactant 0% to 2% Solids: 50% to 54%Formula E Polyurethane Dispersion 50% to 90% Metallic Effect Pigment 18%to 22% Surfactant 0% to 2% Solids: 50% to 54% Formula F Ethylene VinylAcetate (EVA) 94% to 98% Dispersion or EVA Melt Extruded or BlendEVA/EAA or EVA/Surlin Glitter 2% to 6% Solids: 34% to 38% Formula GWater 35% to 39% Isopropyl Alcohol 1% to 5% Polyamide Polymer  3% to 30%Wax  1% to 15% Amine 0% to 2% Ethylene Vinyl Acetate Polymer 13% to 17%Wax  5% to 45% Wax  0% to 17% Water Soluble Polymer  0% to 25%Surfactant 0% to 2% Cationic Polymer  0% to 30% Silicone Wax  0% to 20%Silica  2% to 22% Solids: 31% to 35% Formula H R.O. Water 68% to 72%Water Soluble Polymer 0.2% to 20%  Inorganic Pigment  0% to 25% Silica 1% to 23% Polyamide Polymer  2% to 40% Wax Dispersion 0.5% to 22% Solids: 21% to 25% Formula I Acrylic Acid Copolymer 50% to 97%Dispersion Glow-In-The-Dark Pigment  3% to 25% Solids: 38% to 40%

Closing Notes:

The present image transfer articles, sheets and methods providedecorative effects, that have not been a part of the standard imagetransfer process, incorporating metallic flakes, metallic-like flakes,glitter, sparkle, luminescent materials (e.g., having a glow-in-the-darkeffect), pearlescent materials, reflective materials, or combinationsthereof. Further, the invention allows for a new degree of creativityfor the end user by providing the ability to uniquely create their ownimages by placing the pre-printed or personally made images into theirown design. Accordingly, image transfers that meet high qualitystandards with respect to decorative materials, brightness, coloroptions, uniqueness, clarity without bleeding or mottling, opacity, drystrength and wet strength are now possible.

The above Detailed Description includes references to the accompanyingdrawings, which form a part of the Detailed Description. The drawingsshow, by way of illustration, specific embodiments in which theinvention can be practiced. These embodiments are also referred toherein as “examples.” The present subject matter may be embodied inspecific forms other than those described above or illustrated by theappended drawings. Upon reviewing the present patent document,embodiments and other descriptions of the present subject matter,variations and other implementations that do not depart from the spiritand scope of the present subject matter will be apparent to one ofroutine skill in the this field. Such variations and otherimplementations are considered part of the present invention and withinthe scope of the appended claims.

Referred to herein may be trade names for materials including, but notlimited to, polymers and optional components. The present subject matteris not intended to be limited by the materials described and referencedby a particular trade name. Equivalent materials may be substituted andutilized in the apparatus and methods described herein without departingfrom the scope of the present subject matter.

In this document, the terms “a” or “an” are used, as is common in patentdocuments, to include one or more than one, independent of any otherinstances or usages of “at least one” or “one or more.” In thisdocument, the term “or” is used to refer to a nonexclusive or, such that“A or B” includes “A but not B,” “B but not A,” and “A and B,” unlessotherwise indicated. In this document, references to “an,” “one,” or“various” embodiments are not necessarily to the same embodiment, andsuch references contemplate more than one embodiment. The followingdetailed description is, therefore, not to be taken in a limiting sense,and the scope is defined only by the appended claims, along with thefull scope of legal equivalents to which such claims are entitled.

In the appended claims, the terms “including” and “in which” are used asthe plain-English equivalents of the respective terms “comprising” and“wherein.” Also, in the following claims, the terms “including” and“comprising” are open-ended, that is, a system, assembly, device,article, or process that includes elements in addition to those listedafter such a term in a claim are still deemed to fall within the scopeof that claim. Moreover, in the following claims, the terms “first,”“second,” and “third,” etc. are used merely as labels, and are notintended to impose numerical requirements on their objects.

The Abstract is provided to comply with 37 C.F.R. §1.72(b), to allow thereader to quickly ascertain the nature of the technical disclosure. Itis submitted with the understanding that it will not be used tointerpret or limit the scope or meaning of the claims.

What is claimed is:
 1. An image transfer article, comprising: a resin oradhesive layer; a marking receptive layer configured to receive and totransfer an image to a receptor element, the marking receptive layerformed by at least a solution including water, isopropyl alcohol,particle marble, poly(ethylene oxide) having a molecular weight betweenabout 100,000 to about 8 million, a polyethene wax, and a hot melt; anda decorative layer disposed between the resin or adhesive layer and themarking receptive layer, the decorative layer including one or moretreated mica particles and providing an outwardly-viewable decorativefeature in addition to a received image.
 2. The image transfer articleof claim 1, wherein the decorative layer provides at least one of apearlescent, a metallic, a sparkle, a glow or a luminescentoutwardly-viewable effect.
 3. The image transfer article of claim 1,wherein the decorative layer is non-transparent.
 4. The image transferarticle of claim 1, wherein the one or more treated mica particlesinclude a coating of a metallic effect pigment.
 5. The image transferarticle of claim 4, wherein the metallic effect pigment includes one orboth of titanium dioxide or tin oxide.
 6. The image transfer article ofclaim 1, wherein one or both of the decorative layer or the markingreceptive layer include at least one binding composition configured tochemically bind image ink, the at least one binding composition having aglass transition temperature between about −40° C. to about 30° C. toinhibit flaking or cracking of the image after transfer to the receptorelement.
 7. The image transfer article of claim 1, wherein thedecorative layer further includes a polyurethane or an acrylic material.8. The image transfer article of claim 1, wherein the decorative layerfurther includes carbon black.
 9. The image transfer article of claim 1,wherein one or both of the decorative layer or the marking receptivelayer includes a plurality of metalized polyester or polyethyleneparticles.
 10. The image transfer article of claim 1, wherein one orboth of the decorative layer or the marking receptive layer includes aluminescent pigment.
 11. The image transfer article of claim 1, whereinthe resin or adhesive layer includes at least one of an ethylene acrylicacid or an ethylene-vinyl acetate dispersion, and a wax emulsion. 12.The image transfer article of claim 11, wherein the resin or adhesivelayer includes ethylene-vinyl acetate dispersion and a cross-linkingagent and is configured to accept the received image.
 13. The imagetransfer article of claim 1, wherein the resin or adhesive layerincludes a first surface and a second surface, the decorative layer isadjacent the first surface, the article further comprising a releasableliner or substrate adjacent the second surface of the resin or adhesivelayer.
 14. An image transfer article, comprising: a releasable liner orsubstrate; and a marking receptive layer configured to receive and totransfer an image to a receptor element, the marking receptive layerformed from at least a vanishing layer solution including water,isopropyl alcohol, particle marble, poly(ethylene oxide) having amolecular weight between about 100,000 to about 8 million, apolyethylene wax, and a hot melt, the marking receptive layer configuredto release the received image from the receptor element upon washing thereceptor element a predetermined number of times.
 15. The image transferarticle of claim 14, wherein the marking receptive layer is configuredto dissipate the received image upon one or two washings.
 16. The imagetransfer article of claim 14, wherein the marking receptive layerincludes a thermoplastic, water-soluble resin.
 17. The image transferarticle of claim 16, wherein the thermoplastic, water-soluble resin isink-jet printable.
 18. The image transfer article of claim 16, whereinthe thermoplastic, water-soluble resin has a bond adapted to release themarking receptive layer from the receptor element after thepredetermined number of washings.
 19. A kit comprising: one or moreimage transfer articles as recited in claim 14; and instructions forusing the one or more image transfer articles.
 20. The kit of claim 19,comprising a receptor element upon which to transfer an image disposedon the one or more image transfer articles.
 21. An image transferarticle, comprising: a releasable liner or substrate; and at least onemarking receptive layer formed from a thermoplastic, water soluble resinand a solution comprising water, isopropyl alcohol, particle marble,poly(ethylene oxide) having a molecular weight between about 100,000 toabout 8 million, a polyethylene wax, and a hot melt, wherein the markingreceptive layer is configured to transfer a received image to a receptorelement, the marking receptive layer configured to dissipate thereceived image from the receptor element upon washing the receptorelement a predetermined number of times.
 22. The image transfer articleof claim 21, wherein the marking receptive layer is configured todissipate the received image upon one or two washings.
 23. The imagetransfer article of claim 21, wherein the thermoplastic, water-solubleresin has a bond adapted to release the marking receptive layer from thereceptor element after the predetermined number of washings.